I can't speak for Roy, but I'm not standing here claiming that Powe is a better defender than Davis. I'm simply agreeing that IF Davis is a better defender, then that fact does not manifest itself in the team results. Thus I'm suspicious that when comparing the two, if Powe is better at everything, except that Davis's team defense swings the pendulum in his favor, but there are no indications that his team defense actually is any better, the argument begins to sound specious.
But you are wrong. You are trying to read too much in a merely descriptive metric. The fact that the team allows the opponents to score more when Davis is on the court doesn't mean that Davis superior defense isn't translated to the score. The problem is that you don't know how would the team perform if it was Powe playing those minutes, not Davis. My guess is it'd be worse.
For example, just last season these same numbers were inverted. What's the theory here? That Davis was the superior defender last season but Powe is the better one this season? Why is that?
I'd recommend the reading of Dean Oliver's book. He talks about the dangers of using Defensive Rating (basically the same measurement you're trying to use here, points allowed per 100 possessions when the player is on the floor - he was the one who come up with it) as a measurement of a player's defensive quality.
Others have provided explanations for why the numbers are what they are. IMO, it's very simple: Davis is the more versatile defender, with Powe being a much bigger liability against a wide number of matchups. In some situations where Davis is subpar, Powe would be even worse. This, as you certainly understand, skews the numbers on Powe's favor. The sad truth is that there are no metrics that are remotely useful as ways of rating the defense of a basketball player. Counterparts production (like opponent PER) is an even worse idea: this is basketball, not tennis.
I think Davis is a vastly superior post defender. He's also slightly better on the pick'n'roll and generally shows more awareness and concentration on the defensive side.