Are any of those PGs better? That's incredibly hard to say objectively given how different their playing styles are.
If you were to ask me which of those guys, in a vacuum, would I take over Rondo I think it's an easier question:
I'd take Paul, Irving and Rose over Rondo straight up no problem.
I think Chris Paul is the best PG in the league due to his overall game.
I think Rose and Irving are on the next level behind Paul and Rondo is arguably there too, but at 24 and 21 respectively they've got longer careers ahead of them compared to Rondo at 27. Additionally I think it's easier to build a team around a scoring PG compared to a facilitator like Rondo because it's a more traditional fit and I think it'd be easier finding players who compliment them than Rondo. That isn't to say you can't do that with Rondo, obviously it worked out with KG and PP, it would just be easier.
Westbrook could easily be in the category above, but I'm just not sold on him yet as a centerpiece for a team. Just like Rondo is hard to evaluate given the talent he has to work with, Russell has had Durant and I'd like to see how he would respond when he is the focus of defenses not Durant. I'd probably take him over Rondo, but it would depend on the roster we were putting together.
Parker and Curry are in the next category due to Parker's age and Curry's ankles. I'd say both near Rondo's level, but I wouldn't give him up for either. They're both too risky. Parker played like an MVP at times last year, but is getting to the age where he could start breaking down. Curry broke out last season, but those ankles are too flimsy to count on as a franchise cornerstone.
Lastly I think Deron Williams should probably be on that list. If I had to rank all the nba PGs Williams would have been falling pretty dramatically over the last 2 seasons, but I think that this year with the help he has and the depth I think he is going to reestablish himself as an arguably top 5 pg in the game. He can facilitate and score and with the options he has there should be plenty of room for him to rack up assists and subsequently plenty of opportunities for him to score. I definitely wouldn't trade Rondo straight up for him, but after this season his stock is going to be mighty high.
It's all very subjective but I think Paul is the only clear upgrade and Irving and Rose both have the upside and youth to be worth it. The rest just come with too many caveats.