I think this is tough to generalize about, because so much of it depends on the environment. Now, there may be a point of no return where a guy can't really stop being a chucker, but a lot of these guys are "made" out of necessity.
Brandon Jennings for example has spent the majority of his NBA career on a team with no other real offensive options. The only other above average (or heck, even average) offensive player on the team the last few years was Bogut, and he has been injured half the time. The rest of the guys were terrible offensive players.
Now, things are changing, with Ilyasova emerging and Ellis joining the team, that Jennings has some other options. And it will be interesting to see how he adapts. But I think he was doing exactly what the coach wanted him to for much of his first two seasons.
Another interesting case of this is Austin Rivers. Is he a chucker, or was he playing a role at Duke? Duke was very thin with offensive talent last year, and really needed someone who could create and make shots. And that is what Rivers could do. So, coach K gave him that role, and essentially gave him the green light. With this role, he ended up shooting a relatively low percentage, and has gotten a reputation as a chucker. But the question is, had he not been taking those shots, who would they have gone to, and how much better percentage would they have been?